1. What are Soaps?
Soap is a sodium or potassium salt of a long-chain fatty acid.
Common example: Sodium stearate
(C₁₇H₃₅COONa)
Made by:
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Saponification: Reaction of fat/oil + NaOH/KOH → Soap + Glycerol
Fat/Oil + Alkali (NaOH) → Soap + Glycerol
2. Structure of Soap Molecule
Two parts:
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Hydrophobic (Tail) – long hydrocarbon chain, repels water, attracts dirt/oil.
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Hydrophilic (Head) – ionic part (COO⁻Na⁺), attracts water.
| STRUCTURE OF SOAP |
Dirt/oil is greasy and does not dissolve in water.
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Soap molecules form a micelle:
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Tails trap the dirt/oil.
- Heads face outward, attracting water.
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These micelles lift dirt and rinse it away.
- Micelle: Cluster of soap molecules trapping dirt inside.
4. Limitations of Soaps
Not effective in hard water (water with Ca²⁺ and Mg²⁺ ions).
Forms insoluble scum with these ions and reduces cleaning power.
What are Detergents?
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Detergents are synthetic cleansing agents.
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Made from petrochemicals (not natural fats/oils).
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Example: Sodium lauryl sulfate
Advantages of Detergents
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Work well in hard water
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More foam, more cleaning efficiency
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No scum formation
Anionic – used in laundry (common type)
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Cationic – used in hair conditioners
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Non-ionic – used in dishwashing liquids
| Feature | Soap |
|---|
| Source | Natural oils/fats |
| In Hard Water | Forms scum, less effective |
| Cost | Usually cheaper |
| Environment | Biodegradable |
| Feature | Detergent |
|---|
| Source Petrochemicals (synthetic) |
| In Hard Water | Works well, no scum |
| Cost | Often costlier |
| Environment | Some may not be biodegradable |

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